Photocatalytic degradation of tetracycline-antibiotic under ultraviolet light irradiation using supported TiO2 hierarchical nanoarchitecture
DOI:
https://doi.org/10.37636/recit.v44274286Keywords:
Photocatalysis, TiO2, Tetracycline, UV Radiation, Batch type reactorAbstract
Chrysanthemum- like rutile phase titanium oxide (TiO2) nanoflowers were synthesized on the surface of Raschig borosilicate rings (BRRs). The hierarchical nanoarchitecture was investigated using several physicochemical techniques: scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (IR), diffuse reflectance spectroscopy (DRS), zeta potential (ζ). TiO2-BRR were used as a packed column in a photocatalytic reactor, and their catalytic activity in the degradation of a bacteriostatic antibiotic: tetracycline (C22H24N2O8) was evaluated. The photocatalyst removed 91% of the emerging contaminant achieving an energy efficiency of 68% with an optimized loading of 75 TiO2- BRR and a pH of 4 at 25 ° C; without significant variation in at least three photodegradation cycles. This information can be used to develop supported TiO2 photocatalysts aimed at eliminating emerging contaminants, offering a viable alternative.
Downloads
Metrics
References
T. Larsen, W. Gujer, "The Concept of Sustainable Urban Water Management", Water Science and Technology. Elsevier, vol. 35, no. 9, pp. 3-10, 1997. https://doi.org/10.2166/wst.1997.0326 DOI: https://doi.org/10.2166/wst.1997.0326
J. A. Jaimes Urbina y J. A. Vera Solano, "Los contaminantes emergentes de las aguas residuales de la industria farmacéutica y su tratamiento por medio de la ozonización", Inf. tec., vol. 84, no. 2, pp. 249-263, 2020. https://doi.org/10.23850/22565035.2305 DOI: https://doi.org/10.23850/22565035.2305
A. Pal, Y. He, M. Jekel, M. Reinhard, K. Gin, "Emerging Contaminants of Public Health Significance as Water Quality Indicator Compounds in the Urban Water Cycle", Environment International. Elsevier, vol. 71, pp. 46-62, 2014. https://doi.org/10.1016/j.envint.2014.05.025 DOI: https://doi.org/10.1016/j.envint.2014.05.025
R. Ata, G. Yıldız Töre, "Characterization and Removal of Antibiotic Residues by NFC- Doped Photocatalytic Oxidation from Domestic and Industrial Secondary Treated Wastewaters in Meric-Ergene Basin and Reuse Assessment for Irrigation", J. Environ. Manage. Elsevier, vol. 233, pp. 673-680, 2019. https://doi.org/10.1016/j.jenvman.2018.11.095 DOI: https://doi.org/10.1016/j.jenvman.2018.11.095
Q. Li, R. Jia, J. Shao, Y. He. "Photocatalytic Degradation of Amoxicillin via TiO2 Nanoparticle Coupling with a Novel Submerged Porous Ceramic Membrane Reactor", J. Clean. Prod. Elsevier, vol. 209, 755-761, 2019. https://doi.org/10.1016/j.jclepro.2018.10.183 DOI: https://doi.org/10.1016/j.jclepro.2018.10.183
J. M. Stokes, A.J. Lopatkin, M.A. Lobritz, J.J. Collins. "Bacterial Metabolism and Antibiotic Efficacy". Cell Metab. Elsevier, vol. 30, no. 2, pp. 251-259, 2019. https://doi.org/10.1016/j.cmet.2019.06.009 DOI: https://doi.org/10.1016/j.cmet.2019.06.009
Abu, H. Muhammad, M. Ismail, N, "A Review of Biological Drinking Water Treatment Technologies for Contaminants Removal from Polluted Water Resources". Journal of Water Process Engineering. Elsevier, 33, 101035, 2020. https://doi.org/10.1016/j.jwpe.2019.101035 DOI: https://doi.org/10.1016/j.jwpe.2019.101035
H. Rajput, V. K. Sangal, A. Dhir. "Synthesis of Highly Stable and Efficient Ag Loaded GO/TiO2 Nanotube Electrodes for the Photoelectrocatalytic Degradation of Pentachlorophenol". J. Electroanal. Chem. Elsevier, vol. 814, pp. 118-126, 2018. https://doi.org/10.1016/j.jelechem.2018.02.053 DOI: https://doi.org/10.1016/j.jelechem.2018.02.053
Kumar, J. Bansal, A. ¨CFD Simulations of Immobilized-Titanium Dioxide Based Annular Photocatalytic Reactor: Model Development and Experimental Validation¨. Indian Journal of Chemical Technology. NISCAIR-CSIR, vol. 22, pp. 95-104, 2015.
D. Vaya, P. K. Surolia, "Semiconductor based photocatalytic degradation of pesticides: An overview", Environmental Technology & Innovation. Elsevier, vol. 20, 101128, 2020. https://doi.org/10.1016/j.eti.2020.101128 DOI: https://doi.org/10.1016/j.eti.2020.101128
M. Tahir, S. Tasleem, B. Tahir, "Recent development in band engineering of binary semiconductor materials for solar driven photocatalytic hydrogen production", International Journal of Hydrogen Energy. Elsevier, vol. 45, no. 32, pp. 15985-16038, 2020. https://doi.org/10.1016/j.ijhydene.2020.04.071 DOI: https://doi.org/10.1016/j.ijhydene.2020.04.071
R. Ameta, M. S. Solanki, S. Benjamin, S. C. Ameta. Photocatalysis. In Advanced Oxidation Processes for Waste Water Treatment; Elsevier, pp. 135-175, 2018. https://doi.org/10.1016/B978-0-12-810499-6.00006-1 DOI: https://doi.org/10.1016/B978-0-12-810499-6.00006-1
C. Belver, J. Bedia, A. Gómez-Avilés, M. Peñas-Garzón, J. J. Rodriguez. "Semiconductor Photocatalysis for Water Purification", In Nanoscale Materials in Water Purification. Elsevier, pp 581-651. 2019 https://doi.org/10.1016/B978-0-12-813926-4.00028-8 DOI: https://doi.org/10.1016/B978-0-12-813926-4.00028-8
Alev, O. Şennik, E. Kılınç, N. Öztürk, Z. "Gas Sensor Application of Hydrothermally Growth TiO2 Nanorods", Procedia Engineering. Elsevier, vol. 120, pp. 1162-1165, 2015. https://doi.org/10.1016/j.proeng.2015.08.747 DOI: https://doi.org/10.1016/j.proeng.2015.08.747
M. Hantusch, V. Bessergenev, M. C. Mateus, M. Knupfer, E. Burkel. "Electronic properties of photocatalytic improved Degussa P25 titanium dioxide powder", Catalysis Today. Elsevier, vol. 307, pp. 111-118, 2018. https://doi.org/10.1016/j.cattod.2017.11.005 DOI: https://doi.org/10.1016/j.cattod.2017.11.005
D. A Cruz Rodriguez. Relación Entre Las Propiedades Texturales de Los Recubrimientos de TiO2 Con La Degradación Fotocatalitica de Ácidos Grasos. Centro de Investigación en Materiales Avanzados, S.C.: Chihuahua, 2016.
V. G. Bessergenev, M. C. Mateus, A. M. B. do Rego, M. Hantusch, E. Burkel, "An improvement of photocatalytic activity of TiO2 Degussa P25 powder", Applied Catalysis A: General. Elsevier, vol. 500, pp. 40-50, 2015. https://doi.org/10.1016/j.apcata.2015.05.002 DOI: https://doi.org/10.1016/j.apcata.2015.05.002
V. Parvulescu, M. Ciobanu, G. Petcu, "Handbook of Smart Photocatalytic Materials". Elsevier, Estados Unidos de America, 1er edición 2020.
F. de Brites, A. Polo, A. Benedetti, M. Leão, V. Slusarski-Santana, N. Fernandes, "Evaluation of Photocatalytic Activities of Supported Catalysts on NaX Zeolite or Activated Charcoal", Journal of Hazardous Materials. Elsevier, vol. 263, pp. 61-66, 2013. https://doi.org/10.1016/j.jhazmat.2013.07.061 DOI: https://doi.org/10.1016/j.jhazmat.2013.07.061
Sun, Z. Bai, C. Zheng, S. Yang, X. Frost, R. ¨A Comparative Study of Different Porous Amorphous Silica Minerals Supported TiO2 Catalysts¨. Applied Catalysis A: General. Elsevier, 458, 103-110, 2013. https://doi.org/10.1016/j.apcata.2013.03.035 DOI: https://doi.org/10.1016/j.apcata.2013.03.035
B. Srikanth, R. Goutham, R. Badri Narayan, A. Ramprasath, K. P. Gopinath, A. R. Sankaranarayanan, "Recent advancements in supporting materials for immobilised photocatalytic applications in waste water treatment", Journal of Environmental Management. Elsevier, vol. 200, pp. 60-78. 2017. https://doi.org/10.1016/j.jenvman.2017.05.063 DOI: https://doi.org/10.1016/j.jenvman.2017.05.063
K. P. Sundar, S. Kanmani, "Progression of Photocatalytic Reactors and It's Comparison: A Review", Chem. Eng. Res. Des. Elsevier, vol.154, pp.135-150, 2020. https://doi.org/10.1016/j.cherd.2019.11.035 DOI: https://doi.org/10.1016/j.cherd.2019.11.035
C. Silva, B. Trujillo, R. M.Felix, E. Reynoso, M. Ruiz, "Study of the structure and lattice distortion on the sensing properties of hierarchical rutile TiO2 nanoarchitectures", Functional Materials Letters. World Scientific, vol. 11, no. 4, 2018. https://doi.org/10.1142/S179360471850073X DOI: https://doi.org/10.1142/S179360471850073X
M.M. Ruiz, C. Silva, J.J. Hinostroza, Y.Y. Rivera, P. Valle, B. Trujillo, "Electrochemical sensor for determination of nitrobenzene in aqueous solution based on nanostructures of TiO2/GO", Fuel. Elsevier, vol. 283, no. 119326, 2021. https://doi.org/10.1016/j.fuel.2020.119326 DOI: https://doi.org/10.1016/j.fuel.2020.119326
S. Ikram, J. Jacob, K. Mehboob, K. Mahmood, A. Ashfaq, A. Ali, U. Rehman, "A novel approach to simultaneously enhance the Seebeck coefficient and electrical conductivity in rutile phase of TiO2 nanostructures", Arabian Journal of Chemistry. Elsevier, vol. 13, no. 8, pp. 6724-6729, 2020. https://doi.org/10.1016/j.arabjc.2020.06.026 DOI: https://doi.org/10.1016/j.arabjc.2020.06.026
A. C. Nkele, U. K. Chime, L. Asogwa, A. C. Nwanya, U. Nwankwo, K. Ukoba, F. I. Ezema, "A Study on Titanium Dioxide Nanoparticles Synthesized from Titanium Isopropoxide Under SILAR-Induced Gel Method: Transition from Anatase to Rutile Structure¨, Inorganic Chemistry Communications. Elsevier, vol. 112, no. 107705, 2020. https://doi.org/10.1016/j.inoche.2019.107705 DOI: https://doi.org/10.1016/j.inoche.2019.107705
J. Singh, S. Sharma, S. Sharma, R. C Singh, "Effect of tungsten doping on structural and optical properties of rutile TiO2 and band gap narrowing", Optik. Elsevier, vol. 182, pp. 538-547, 2019. https://doi.org/10.1016/j.ijleo.2019.01.070 DOI: https://doi.org/10.1016/j.ijleo.2019.01.070
J. M Calatayud, "Síntesis y Caracterización de Nanopartículas de TiO2 y ZrO2 Dopadas Con Cationes de Metales de Transición. Aplicaciones Como Nanopigmentos y En Fotocatálisis", Universitat de València: Valencia, 2017.
S. Estrada-Flores, A Martínez-Luévanos, L. A. García-Cerda, C. M. Pérez-Berumen, T. E. Flores-Guia, E. Aguilera-González, "Síntesis de Partículas Mesoporosas de TiO2 y Estudio Cinético de La Fotodegradación de Azul de Metileno", Rev. Int. Investig. e Innovación Tecnológica, vol. 7, no. 42, pp. 1-13, 2020.
H. Rajput, V. K. Sangal, A. Dhir, "Synthesis of highly stable and efficient Ag loaded GO/TiO2 nanotube electrodes for the photoelectrocatalytic degradation of pentachlorophenol", Journal of Electroanalytical Chemistry. Elsevier, vol. 814, pp. 118-126, 2018. https://doi.org/10.1016/j.jelechem.2018.02.053 DOI: https://doi.org/10.1016/j.jelechem.2018.02.053
S. B. Wategaonkar, R. P. Pawar, V. G. Parale, D. P. Nade, B. M. Sargar, R. K. Mane, single step hydrothermal route and its characterization", Materials Today: Proceedings. Elsevier, vol. 23, pp. 444-451, 2020. https://doi.org/10.1016/j.matpr.2020.02.065 DOI: https://doi.org/10.1016/j.matpr.2020.02.065
T. Wan, S. Lu, W. Cheng, J. Ren, M. Wang, B. Hu, Y. Sun, "A spectroscopic and theoretical investigation of interaction mechanisms of tetracycline and polystyrene nanospheres Pollution. Elsevier, vol. 249, pp. 398-405, 2019. https://doi.org/10.1016/j.envpol.2019.03.049 DOI: https://doi.org/10.1016/j.envpol.2019.03.049
A. A. Mohammed, S. L. Kareem, "Adsorption of tetracycline from wastewater by using Pistachio shell coated with ZnO nanoparticles: Equilibrium, kinetic and isotherm studies", Alexandria Engineering Journal. Elsevier, vol. 58, no. 3, pp. 917-928, 2019. https://doi.org/10.1016/j.aej.2019.08.006 DOI: https://doi.org/10.1016/j.aej.2019.08.006
Published
How to Cite
Issue
Section
Categories
License
Copyright (c) 2021 Juan José Hinostroza Mojarro, Francisco Javier García Picazo, Mirza Mariela Ruiz Ramirez, Karen Melisa Luque López, Balter Trujillo Navarrete
This work is licensed under a Creative Commons Attribution 4.0 International License.
The authors who publish in this journal accept the following conditions:
The authors retain the copyright and assign to the journal the right of the first publication, with the work registered with the Creative Commons Attribution license 4.0, which allows third parties to use what is published as long as they mention the authorship of the work and the first publication in this magazine.
Authors may make other independent and additional contractual agreements for the non-exclusive distribution of the version of the article published in this journal (eg, include it in an institutional repository or publish it in a book) as long as they clearly indicate that the work it was first published in this magazine.
Authors are allowed and encouraged to share their work online (for example: in institutional repositories or personal web pages) before and during the manuscript submission process, as it can lead to productive exchanges, greater and more quick citation of published work (see The Effect of Open Access).
