Evaluación de polisacáridos en floculación mediada por complejo polielectrolítico

Authors

  • Mercedes Teresita Oropeza-Guzmán Tecnológico Nacional de México/I. T. Tijuana. Centro de Graduados e Investigación en Química-Grupo de Biomateriales y Nanomedicina
  • Fernanda Araiza-Verduzco Facultad de Odontología, Universidad Autónoma de Baja California, Campus Tijuana, Calzada Universidad 14418, 22390 Tijuana, BC, México https://orcid.org/0000-0003-2426-7896

DOI:

https://doi.org/10.37636/recit.v6n2e247

Keywords:

Polysaccharide, Flocculation, Polyelectrolyte complex, water treatment

Abstract

Water is an increasingly valuable resource because its availability, primarily it is limited to precipitation and water storage; for that reason, increasing population density and climate change can interfere with water accessibility. Urban and industrial activities can produce wastewater and pollute waterbodies that could represent a significant water source; however, it needs to be treated prior to its use.  Flocculation is an important pollutants removal method to reduce a variety of organic and inorganic molecules from wastewater, using the flocculant’s intrinsic charges to stabilize/precipitate them, by different methods, one of them being via polyelectrolyte complex. Flocculant versatility depends on its capacity to remove pollutants and there are commercial flocculants with remarkable efficiencies. However, their toxicity can limit their use in waterbodies or for former human use. Research shows that polysaccharides are great option as flocculants because of their easily charged conformation and high molecular weight to neutralize pollutants and precipitate flocs, they are biocompatible, biodegradable, and easy to modify to modulate the flocculant interaction due to the functional group’s high density. This review explores the latest research on polysaccharide polyelectrolyte flocculation and derivatives and their pollutant removal capacity, the polysaccharides evaluated were the most commonly researched such as chitosan, cellulose, chitin, alginate, gums, dextran, among others. Recent research tendencies on these polysaccharides flocculation capacity, showed promising results (up to 99% removal efficiencies) with a wide variety of contaminants, making them excellent candidates for their application in green flocculation.

Downloads

Download data is not yet available.

References

M. De Sanctis, G. Del Moro, S. Chimienti, P. Ritelli, C. Levantesi, and C. Di Iaconi, "Removal of pollutants and pathogens by a simplified treatment scheme for municipal wastewater reuse in agriculture," Science of The Total Environment, vol. 580, pp. 17-25, 2017, doi: https://doi.org/10.1016/j.scitotenv.2016.12.002. DOI: https://doi.org/10.1016/j.scitotenv.2016.12.002

M. Hossain and P. K. Patra, "Water pollution index – A new integrated approach to rank water quality," Ecological Indicators, vol. 117, p. 106668, 2020, doi: https://doi.org/10.1016/j.ecolind.2020.106668. DOI: https://doi.org/10.1016/j.ecolind.2020.106668

M. Salgot and M. Folch, "Wastewater treatment and water reuse," Current Opinion in Environmental Science & Health, vol. 2, pp. 64-74, 2018, doi: https://doi.org/10.1016/j.coesh.2018.03.005. DOI: https://doi.org/10.1016/j.coesh.2018.03.005

V. Gitis and N. Hankins, "Water treatment chemicals: Trends and challenges," Journal of Water Process Engineering, vol. 25, pp. 34-38, 2018, doi: https://doi.org/10.1016/j.jwpe.2018.06.003. DOI: https://doi.org/10.1016/j.jwpe.2018.06.003

J. Gregory and C. R. O'Melia, "Fundamentals of flocculation," Critical Reviews in Environmental Control, vol. 19, no. 3, pp. 185-230, 1989, doi: https://doi.org/10.1080/10643388909388365. DOI: https://doi.org/10.1080/10643388909388365

R. I. Feigin and D. H. Napper, "Depletion stabilization and depletion flocculation," Journal of Colloid and Interface Science, vol. 75, no. 2, pp. 525-541, 1980, doi: https://doi.org/10.1016/0021-9797(80)90475-0. DOI: https://doi.org/10.1016/0021-9797(80)90475-0

E. Dickinson and L. Eriksson, "Particle flocculation by adsorbing polymers," Advances in Colloid and Interface Science, vol. 34, pp. 1-29, 1991, doi: https://doi.org/10.1016/0001-8686(91)80045-L. DOI: https://doi.org/10.1016/0001-8686(91)80045-L

Y. Ghimire and A. Bhattarai, "A Review on Polyelectrolytes (PES) and Polyelectrolyte Complexes (PECs)," International Journal of Engineering and Technical Research, vol. 9, 2021, doi: https://doi.org/10.1016/j.chemosphere.2023.138418. DOI: https://doi.org/10.17577/IJERTV9IS080112

G. Petzold and S. Schwarz, "Polyelectrolyte Complexes in Flocculation Applications," Advances in Polymer Science, vol. 256, pp. 25-66, 2014, doi: https://doi.org/10.1007/12_2012_205. DOI: https://doi.org/10.1007/12_2012_205

R.-J. Leu and M. M. Ghosh, "Polyelectrolyte Characteristics and Flocculation," Journal (American Water Works Association), vol. 80, no. 4, pp. 159-167, 1988. [Online]. Available: http://www.jstor.org/stable/41292143. DOI: https://doi.org/10.1002/j.1551-8833.1988.tb03021.x

M. Stornes, B. Shrestha, and R. S. Dias, "pH-Dependent Polyelectrolyte Bridging of Charged Nanoparticles," The Journal of Physical Chemistry B, vol. 122, no. 44, pp. 10237-10246, 2018, doi: https://doi.org/10.1021/acs.jpcb.8b06971. DOI: https://doi.org/10.1021/acs.jpcb.8b06971

G. Chakraborty, A. Bhattarai, and R. De, "Polyelectrolyte-Dye Interactions: An Overview," Polymers, vol. 14, no. 3, 2022, doi: https://doi.org/10.3390/polym14030598. DOI: https://doi.org/10.3390/polym14030598

M. G. Rasteiro, F. A. P. Garcia, P. J. Ferreira, E. Antunes, D. Hunkeler, and C. Wandrey, "Flocculation by cationic polyelectrolytes: Relating efficiency with polyelectrolyte characteristics," Journal of Applied Polymer Science, vol. 116, no. 6, pp. 3603-3612, 2010, doi: https://doi.org/10.1002/app.31903. DOI: https://doi.org/10.1002/app.31903

D. A. Mortimer, "Synthetic polyelectrolytes—A review," Polymer International, vol. 25, no. 1, pp. 29-41, 1991, doi: https://doi.org/10.1002/pi.4990250107. DOI: https://doi.org/10.1002/pi.4990250107

Y. Kamiyama and J. Israelachvili, "Effect of pH and salt on the adsorption and interactions of an amphoteric polyelectrolyte," Macromolecules, vol. 25, no. 19, pp. 5081-5088, 1992, doi: https://doi.org/10.1021/ma00045a039. DOI: https://doi.org/10.1021/ma00045a039

I. Pinheiro et al., "An experimental design methodology to evaluate the importance of different parameters on flocculation by polyelectrolytes," Powder Technology, vol. 238, pp. 2-13, 2013, doi: https://doi.org/10.1016/j.powtec.2012.08.004. DOI: https://doi.org/10.1016/j.powtec.2012.08.004

D. N. Thomas, S. J. Judd, and N. Fawcett, "Flocculation modelling: a review," Water Research, vol. 33, no. 7, pp. 1579-1592, 1999, doi: https://doi.org/10.1016/S0043-1354(98)00392-3. DOI: https://doi.org/10.1016/S0043-1354(98)00392-3

J. C. Winterwerp et al., "Flocculation and settling velocity of fine sediment," Proceedings in Marine Science, vol. 5, pp. 25-40, 2002, doi: https://doi.org/10.1016/S1568-2692(02)80006-7. DOI: https://doi.org/10.1016/S1568-2692(02)80006-7

J. Sun, X. Zhang, X. Miao, and J. Zhou, "Preparation and characteristics of bioflocculants from excess biological sludge," Bioresource Technology, vol. 126, pp. 362-366, 2012, doi: https://doi.org/10.1016/j.biortech.2012.08.042. DOI: https://doi.org/10.1016/j.biortech.2012.08.042

J. H. Park, C. Oh, Y.-S. Han, and S.-W. Ji, "Optimizing the addition of flocculants for recycling mineral-processing wastewater," Geosystem Engineering, vol. 19, no. 2, pp. 83-88, 2016, doi: https://doi.org/10.1080/12269328.2015.1099478. DOI: https://doi.org/10.1080/12269328.2015.1099478

H. Takigami, N. Taniguchi, Y. Shimizu, and S. Matsui, "Toxicity assays and their evaluation on organic polymer flocculants used for municipal sludge dewatering," Water Science and Technology, vol. 38, no. 7, pp. 207-215, 1998, doi: https://doi.org/10.1016/S0273-1223(98)00622-2. DOI: https://doi.org/10.2166/wst.1998.0294

K. Iwuozor, "Prospects and Challenges of Using Coagulation-Flocculation Method in the Treatment of Effluents," Advanced Journal of Chemistry-Section A, vol. 2, pp. 105-127, 01/27 2019, doi: https://doi.org/10.29088/SAMI/AJCA.2019.2.105127. DOI: https://doi.org/10.29088/SAMI/AJCA.2019.2.105127

T. T. H. Nguyen et al., "Introduction to polysaccharides," Food, Medical, and Environmental Applications of Polysaccharides, pp. 3-46, 2021, doi: https://doi.org/10.1016/B978-0-12-819239-9.00002-6. DOI: https://doi.org/10.1016/B978-0-12-819239-9.00002-6

M. Jin, J. Shi, W. Zhu, H. Yao, and D. A. Wang, "Polysaccharide-Based Biomaterials in Tissue Engineering: A Review," Tissue Eng Part B Rev, vol. 27, no. 6, pp. 604-626, 2021, doi: https://doi.org/10.1089/ten.TEB.2020.0208. DOI: https://doi.org/10.1089/ten.teb.2020.0208

A. S. A. Mohammed, M. Naveed, and N. Jost, "Polysaccharides; Classification, Chemical Properties, and Future Perspective Applications in Fields of Pharmacology and Biological Medicine (A Review of Current Applications and Upcoming Potentialities)," Journal of Polymers and the Environment, vol. 29, no. 8, pp. 2359-2371, 2021, doi: https://doi.org/10.1007/s10924-021-02052-2. DOI: https://doi.org/10.1007/s10924-021-02052-2

Z. Souguir, E. About-Jaudet, L. Picton, and D. Le Cerf, "Anionic Polysaccharide Hydrogels with Charges Provided by the Polysaccharide or the Crosslinking Agent," Drug Delivery Letters, vol. 2, pp. 240-250, 12/01 2012, doi: https://doi.org/10.2174/2210304x11202040002. DOI: https://doi.org/10.2174/2210304x11202040002

I. Cumpstey, "Chemical Modification of Polysaccharides," ISRN Organic Chemistry, vol. 2013, p. 417672, 2013, doi: https://doi.org/10.1155/2013/417672. DOI: https://doi.org/10.1155/2013/417672

R. Krishnaswamy and A. Ayoub, "Recent Advances in Cationic and Anionic Polysaccharides Fibers," in Polysaccharide-based Fibers and Composites: Chemical and Engineering Fundamentals and Industrial Applications, L. Lucia and A. Ayoub Eds. Cham: Springer International Publishing, 2018, pp. 63-75. DOI: https://doi.org/10.1007/978-3-319-56596-5_4

L. Li, H. Zhang, and G. Pan, "Influence of zeta potential on the flocculation of cyanobacteria cells using chitosan modified soil," Journal of Environmental Sciences, vol. 28, pp. 47-53, 2015, doi: https://doi.org/10.1016/j.jes.2014.04.017. DOI: https://doi.org/10.1016/j.jes.2014.04.017

J. Blockx, A. Verfaillie, W. Thielemans, and K. Muylaert, "Unravelling the Mechanism of Chitosan-Driven Flocculation of Microalgae in Seawater as a Function of pH," ACS Sustainable Chemistry & Engineering, vol. 6, no. 9, pp. 11273-11279, 2018, doi: https://doi.org/10.1021/acssuschemeng.7b04802. DOI: https://doi.org/10.1021/acssuschemeng.7b04802

Y. Sun, K. J. Shah, W. Sun, and H. Zheng, "Performance evaluation of chitosan-based flocculants with good pH resistance and high heavy metals removal capacity," Separation and Purification Technology, vol. 215, pp. 208-216, 2019, doi: https://doi.org/10.1016/j.seppur.2019.01.017. DOI: https://doi.org/10.1016/j.seppur.2019.01.017

I. Aranaz et al., "Chitosan: An Overview of Its Properties and Applications," Polymers, vol. 13, no. 19, doi: https://doi.org/10.3390/polym13193256.

J. Wang and S. Zhuang, "Chitosan-based materials: Preparation, modification and application," Journal of Cleaner Production, vol. 355, p. 131825, 2022, doi: https://doi.org/10.1016/j.jclepro.2022.131825. DOI: https://doi.org/10.1016/j.jclepro.2022.131825

P. S. Bakshi, D. Selvakumar, K. Kadirvelu, and N. S. Kumar, "Chitosan as an environment friendly biomaterial – a review on recent modifications and applications," International Journal of Biological Macromolecules, vol. 150, pp. 1072-1083, 2020, doi: https://doi.org/10.1016/j.ijbiomac.2019.10.113. DOI: https://doi.org/10.1016/j.ijbiomac.2019.10.113

C. P. Jiménez-Gómez and J. A. Cecilia, "Chitosan: A Natural Biopolymer with a Wide and Varied Range of Applications," Molecules, vol. 25, no. 17, p. 3981, 2020, doi: https://doi.org/10.3390/molecules25173981. DOI: https://doi.org/10.3390/molecules25173981

P. Loganathan, M. Gradzielski, H. Bustamante, and S. Vigneswaran, "Progress, challenges, and opportunities in enhancing NOM flocculation using chemically modified chitosan: a review towards future development," Environmental Science: Water Research & Technology, vol. 6, no. 1, pp. 45-61, 2020, doi: https://doi.org/10.1039/C9EW00596J. DOI: https://doi.org/10.1039/C9EW00596J

I. Aranaz et al., "Chitosan: An Overview of Its Properties and Applications," Polymers, vol. 13, no. 19, 2021, doi: https://doi.org/10.3390/polym13193256. DOI: https://doi.org/10.3390/polym13193256

S. Bhalkaran and L. D. Wilson, "Investigation of Self-Assembly Processes for Chitosan-Based Coagulant-Flocculant Systems: A Mini-Review," Int J Mol Sci, vol. 17, no. 10, p. 1662, 2016, doi: https://doi.org/10.3390/ijms17101662. DOI: https://doi.org/10.3390/ijms17101662

L. Chen, D. Chen, and W. Chongliang, "A New Approach for the Flocculation Mechanism of Chitosan," Journal of Polymers and the Environment, vol. 11, pp. 87-92, 2003, doi: https://doi.org/10.1023/A:1024656813244. DOI: https://doi.org/10.1023/A:1024656813244

R. Rojas-Reyna, S. Schwarz, G. Heinrich, G. Petzold, S. Schütze, and J. Bohrisch, "Flocculation efficiency of modified water soluble chitosan versus commonly used commercial polyelectrolytes," Carbohydrate Polymers, vol. 81, no. 2, pp. 317-322, 2010, doi: https://doi.org/10.1016/j.carbpol.2010.02.010. DOI: https://doi.org/10.1016/j.carbpol.2010.02.010

J. L. Sanchez-Salvador, A. Balea, M. C. Monte, C. Negro, and A. Blanco, "Chitosan grafted/cross-linked with biodegradable polymers: A review," International Journal of Biological Macromolecules, vol. 178, pp. 325-343, 2021, doi: https://doi.org/10.1016/j.ijbiomac.2021.02.200. DOI: https://doi.org/10.1016/j.ijbiomac.2021.02.200

R. Yang, H. Li, M. Huang, H. Yang, and A. Li, "A review on chitosan-based flocculants and their applications in water treatment," Water Research, vol. 95, pp. 59-89, 2016, doi: https://doi.org/10.1016/j.watres.2016.02.068. DOI: https://doi.org/10.1016/j.watres.2016.02.068

R. Divakaran and V. N. Sivasankara Pillai, "Flocculation of river silt using chitosan," Water Research, vol. 36, no. 9, pp. 2414-2418, 2002, doi: https://doi.org/10.1016/S0043-1354(01)00436-5. DOI: https://doi.org/10.1016/S0043-1354(01)00436-5

Z. Yang et al., "Role of moderately hydrophobic chitosan flocculants in the removal of trace antibiotics from water and membrane fouling control," Water Research, vol. 177, p. 115775, 2020, doi: https://doi.org/10.1016/j.watres.2020.115775. DOI: https://doi.org/10.1016/j.watres.2020.115775

E. Guibal and J. Roussy, "Coagulation and flocculation of dye-containing solutions using a biopolymer (Chitosan)," Reactive and Functional Polymers, vol. 67, no. 1, pp. 33-42, 2007, doi: https://doi.org/10.1016/j.reactfunctpolym.2006.08.008. DOI: https://doi.org/10.1016/j.reactfunctpolym.2006.08.008

Y. Wu et al., "Efficient removal of both positively and negatively charged colloidal contaminants using amphoteric starch-based flocculants synthesized by low-pressure UV initiation," Separation and Purification Technology, vol. 282, p. 120120, 2022, doi: https://doi.org/10.1016/j.seppur.2021.120120. DOI: https://doi.org/10.1016/j.seppur.2021.120120

B. Liu et al., "Rapid and efficient removal of heavy metal and cationic dye by carboxylate-rich magnetic chitosan flocculants: Role of ionic groups," Carbohydrate Polymers, vol. 181, pp. 327-336, 2018, doi: https://doi.org/10.1016/j.carbpol.2017.10.089. DOI: https://doi.org/10.1016/j.carbpol.2017.10.089

F. Renault, B. Sancey, P. M. Badot, and G. Crini, "Chitosan for coagulation/flocculation processes – An eco-friendly approach," European Polymer Journal, vol. 45, no. 5, pp. 1337-1348, 2009, doi: https://doi.org/10.1016/j.eurpolymj.2008.12.027. DOI: https://doi.org/10.1016/j.eurpolymj.2008.12.027

B. Liu et al., "A novel carboxyl-rich chitosan-based polymer and its application for clay flocculation and cationic dye removal," Science of The Total Environment, vol. 640-641, pp. 107-115, 2018, doi: https://doi.org/10.1016/j.scitotenv.2018.05.309. DOI: https://doi.org/10.1016/j.scitotenv.2018.05.309

X. Tang, T. Huang, S. Zhang, J. Zheng, and H. Zheng, "Synthesis of an amphoteric chitosan-based flocculant and its flocculation performance in the treatment of dissolved organic matter from drinking water," Desalination and Water Treatment, vol. 174, pp. 171-177, 2020, doi: https://doi.org/10.5004/dwt.2020.24852. DOI: https://doi.org/10.5004/dwt.2020.24852

Y. Sun et al., "Novel chitosan-based flocculants for chromium and nickle removal in wastewater via integrated chelation and flocculation," Journal of Environmental Management, vol. 248, p. 109241, 2019, doi: https://doi.org/10.1016/j.jenvman.2019.07.012. DOI: https://doi.org/10.1016/j.jenvman.2019.07.012

H. K. Agbovi and L. D. Wilson, "Design of amphoteric chitosan flocculants for phosphate and turbidity removal in wastewater," Carbohydrate Polymers, vol. 189, pp. 360-370, 2018, doi: https://doi.org/10.1016/j.carbpol.2018.02.024. DOI: https://doi.org/10.1016/j.carbpol.2018.02.024

T. Lü, C. Luo, D. Qi, D. Zhang, and H. Zhao, "Efficient treatment of emulsified oily wastewater by using amphipathic chitosan-based flocculant," Reactive and Functional Polymers, vol. 139, pp. 133-141, 2019, doi: https://doi.org/10.1016/j.reactfunctpolym.2019.03.019. DOI: https://doi.org/10.1016/j.reactfunctpolym.2019.03.019

D. Elieh-Ali-Komi and M. R. Hamblin, "Chitin and Chitosan: Production and Application of Versatile Biomedical Nanomaterials," (in eng), Int J Adv Res (Indore), vol. 4, no. 3, pp. 411-427, 2016. [Online]. Available: https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5094803/.

R. Wijesena, N. Tissera, V. W. S. G. Rathnayaka, P. de Silva, and P. de Silva, "Colloidal stability of chitin nanofibers in aqueous systems: Effect of pH, ionic strength, temperature & concentration," Carbohydrate Polymers, vol. 235, p. 116024, 2020, doi: https://doi.org/10.1016/j.carbpol.2020.116024. DOI: https://doi.org/10.1016/j.carbpol.2020.116024

G. L. Dotto, G. S. Rosa, M. A. Moraes, R. F. Weska, and L. A. A. Pinto, "Treatment of chitin effluents by coagulation–flocculation with chitin and aluminum sulfate," Journal of Environmental Chemical Engineering, vol. 1, no. 1, pp. 50-55, 2013, doi: https://doi.org/10.1016/j.jece.2013.03.006. DOI: https://doi.org/10.1016/j.jece.2013.03.006

R. Zhao et al., "Chitin-biocalcium as a novel superior composite for ciprofloxacin removal: Synergism of adsorption and flocculation," Journal of Hazardous Materials, vol. 423, p. 126917, 2022, doi: https://doi.org/10.1016/j.jhazmat.2021.126917. DOI: https://doi.org/10.1016/j.jhazmat.2021.126917

Y. Sun et al., "Functionalized chitosan-magnetic flocculants for heavy metal and dye removal modeled by an artificial neural network," Separation and Purification Technology, vol. 282, p. 120002, 2022, doi: https://doi.org/10.1016/j.seppur.2021.120002. DOI: https://doi.org/10.1016/j.seppur.2021.120002

M. Liu, Y. Guo, J. Lan, Y. Zhou, Q. Dong, and C. Guo, "Synthesis of Ce/SiO2 Composited Cross-Linked Chitosan Flocculation Material and Its Application in Decolorization of Tartrazine Dye," ChemistrySelect, vol. 4, no. 45, pp. 13156-13162, 2019, doi: https://doi.org/10.1002/slct.201903312. DOI: https://doi.org/10.1002/slct.201903312

L. Feng et al., "Preparation of a graft modified flocculant based on chitosan by ultrasonic initiation and its synergistic effect with kaolin for the improvement of acid blue 83 (AB 83) removal," International Journal of Biological Macromolecules, vol. 150, pp. 617-630, 2020, doi: https://doi.org/10.1016/j.ijbiomac.2020.02.076. DOI: https://doi.org/10.1016/j.ijbiomac.2020.02.076

E. Hermosillo-Ochoa, L. A. Picos-Corrales, and A. Licea-Claverie, "Eco-friendly flocculants from chitosan grafted with PNVCL and PAAc: Hybrid materials with enhanced removal properties for water remediation," Separation and Purification Technology, vol. 258, p. 118052, 2021, doi: https://doi.org/10.1016/j.seppur.2020.118052. DOI: https://doi.org/10.1016/j.seppur.2020.118052

Y. Sun, W. Sun, K. J. Shah, P.-C. Chiang, and H. Zheng, "Characterization and flocculation evaluation of a novel carboxylated chitosan modified flocculant by UV initiated polymerization," Carbohydrate Polymers, vol. 208, pp. 213-220, 2019, doi: https://doi.org/10.1016/j.carbpol.2018.12.064. DOI: https://doi.org/10.1016/j.carbpol.2018.12.064

X. Tang, T. Huang, S. Zhang, W. Wang, and H. Zheng, "The role of sulfonated chitosan-based flocculant in the treatment of hematite wastewater containing heavy metals," Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 585, p. 124070, 2020, doi: https://doi.org/10.1016/j.colsurfa.2019.124070. DOI: https://doi.org/10.1016/j.colsurfa.2019.124070

Y. Sun, S. Zhou, W. Sun, S. Zhu, and H. Zheng, "Flocculation activity and evaluation of chitosan-based flocculant CMCTS-g-P(AM-CA) for heavy metal removal," Separation and Purification Technology, vol. 241, p. 116737, 2020, doi: https://doi.org/10.1016/j.seppur.2020.116737. DOI: https://doi.org/10.1016/j.seppur.2020.116737

Y. Sun, D. Li, X. Lu, J. Sheng, X. Zheng, and X. Xiao, "Flocculation of combined contaminants of dye and heavy metal by nano-chitosan flocculants," Journal of Environmental Management, vol. 299, p. 113589, 2021, doi: https://doi.org/10.1016/j.jenvman.2021.113589. DOI: https://doi.org/10.1016/j.jenvman.2021.113589

Y. Sun, Y. Yu, X. Zheng, A. Chen, and H. Zheng, "Magnetic flocculation of Cu(II) wastewater by chitosan-based magnetic composite flocculants with recyclable properties," Carbohydrate Polymers, vol. 261, p. 117891, 2021, doi: https://doi.org/10.1016/j.carbpol.2021.117891. DOI: https://doi.org/10.1016/j.carbpol.2021.117891

J. Ma et al., "Flocculation of emulsified oily wastewater by using functional grafting modified chitosan: The effect of cationic and hydrophobic structure," Journal of Hazardous Materials, vol. 403, p. 123690, 2021, doi: https://doi.org/10.1016/j.jhazmat.2020.123690. DOI: https://doi.org/10.1016/j.jhazmat.2020.123690

Z. Wang et al., "Influence of DOM characteristics on the flocculation removal of trace pharmaceuticals in surface water by the successive dosing of alum and moderately hydrophobic chitosan," Water Research, vol. 213, p. 118163, 2022, doi: https://doi.org/10.1016/j.watres.2022.118163. DOI: https://doi.org/10.1016/j.watres.2022.118163

H. P. Vu, L. N. Nguyen, G. Lesage, and L. D. Nghiem, "Synergistic effect of dual flocculation between inorganic salts and chitosan on harvesting microalgae Chlorella vulgaris," Environmental Technology & Innovation, vol. 17, p. 100622, 2020, doi: https://doi.org/10.1016/j.eti.2020.100622. DOI: https://doi.org/10.1016/j.eti.2020.100622

Q. Wang, K. Oshita, and M. Takaoka, "Flocculation properties of eight microalgae induced by aluminum chloride, chitosan, amphoteric polyacrylamide, and alkaline: Life-cycle assessment for screening species and harvesting methods," Algal Research, vol. 54, p. 102226, 2021, doi: https://doi.org/10.1016/j.algal.2021.102226. DOI: https://doi.org/10.1016/j.algal.2021.102226

E. T. Chua, E. Eltanahy, H. Jung, M. Uy, S. R. Thomas-Hall, and P. M. Schenk, "Efficient Harvesting of Nannochloropsis Microalgae via Optimized Chitosan-Mediated Flocculation," Global Challenges, vol. 3, no. 1, p. 1800038, 2019, doi: https://doi.org/10.1002/gch2.201800038. DOI: https://doi.org/10.1002/gch2.201800038

T. S. Frantz, B. S. d. Farias, V. R. M. Leite, F. Kessler, T. R. S. A. Cadaval Jr, and L. A. d. A. Pinto, "Preparation of new biocoagulants by shrimp waste and its application in coagulation-flocculation processes," Journal of Cleaner Production, vol. 269, p. 122397, 2020, doi: https://doi.org/10.1016/j.jclepro.2020.122397. DOI: https://doi.org/10.1016/j.jclepro.2020.122397

T. Zeng, X.-q. Hu, H. Wu, J.-w. Yang, and H.-b. Zhang, "Microwave assisted synthesis and characterization of a novel bio-based flocculant from dextran and chitosan," International Journal of Biological Macromolecules, vol. 131, pp. 760-768, 2019, doi: https://doi.org/10.1016/j.ijbiomac.2019.03.116. DOI: https://doi.org/10.1016/j.ijbiomac.2019.03.116

Z. Tian, L. Zhang, X. Sang, G. Shi, and C. Ni, "Preparation and flocculation performance study of a novel amphoteric alginate flocculant," Journal of Physics and Chemistry of Solids, vol. 141, p. 109408, 2020, doi: https://doi.org/10.1016/j.jpcs.2020.109408. DOI: https://doi.org/10.1016/j.jpcs.2020.109408

Z. Tian, L. Zhang, G. Shi, X. Sang, and C. Ni, "The synthesis of modified alginate flocculants and their properties for removing heavy metal ions of wastewater," Journal of Applied Polymer Science, vol. 135, no. 31, p. 46577, 2018, doi: https://doi.org/10.1002/app.46577. DOI: https://doi.org/10.1002/app.46577

Z. Tian, L. Zhang, and C. Ni, "Preparation and flocculation properties of modified alginate amphiphilic polymeric nano-flocculants," Environmental Science and Pollution Research, vol. 26, no. 31, pp. 32397-32406, 2019, doi: https://doi.org/10.1007/s11356-019-06308-2. DOI: https://doi.org/10.1007/s11356-019-06308-2

G. Craciun, E. Manaila, and D. Ighigeanu, "New Type of Sodium Alginate-g-acrylamide Polyelectrolyte Obtained by Electron Beam Irradiation: Characterization and Study of Flocculation Efficacy and Heavy Metal Removal Capacity," Polymers, vol. 11, no. 2, doi: https://doi.org/10.3390/polym11020234.

Y. Liu et al., "Flocculation performance of alginate grafted polysilicate aluminum calcium in drinking water treatment," Process Safety and Environmental Protection, vol. 155, pp. 287-294, 2021, doi: https://doi.org/10.1016/j.psep.2021.09.012. DOI: https://doi.org/10.1016/j.psep.2021.09.012

A. A. Elfoulani, O. Ounas, A. Laabi, B. Lekhlif, and J. E. Jamal, "Removal of dissolved and colloidal matter from surface waters by composite flocculant aluminium salt-sodium alginate," DESALINATION AND WATER TREATMENT, vol. 207, pp. 108-114, 2020, doi: https://doi.org/10.5004/dwt.2020.26407. DOI: https://doi.org/10.5004/dwt.2020.26407

H. Maruyama, H. Seki, and A. Igi, "Flocculation of quartz and kaolin by alginate-protamine complex," Biochemical Engineering Journal, vol. 162, p. 107713, 2020, doi: https://doi.org/10.1016/j.bej.2020.107713. DOI: https://doi.org/10.1016/j.bej.2020.107713

G. Craciun, E. Manaila, and D. Ighigeanu, "Flocculant Based on Acrylamide and Acrylic Acid Grafted on Sodium Alginate by Electron Beam Irradiation," Materiale Plastice, vol. 56, pp. 124-128, 2019, doi: https://doi.org/10.37358/MP.19.1.5136. DOI: https://doi.org/10.37358/MP.19.1.5136

X. Zhao, X. Wang, G. Song, and T. Lou, "Microwave assisted copolymerization of sodium alginate and dimethyl diallyl ammonium chloride as flocculant for dye removal," International Journal of Biological Macromolecules, vol. 156, pp. 585-590, 2020, doi: https://doi.org/10.1016/j.ijbiomac.2020.04.054. DOI: https://doi.org/10.1016/j.ijbiomac.2020.04.054

H. Zhang, G. Guan, T. Lou, and X. Wang, "High performance, cost-effective and ecofriendly flocculant synthesized by grafting carboxymethyl cellulose and alginate with itaconic acid," International Journal of Biological Macromolecules, vol. 231, p. 123305, 2023, doi: https://doi.org/10.1016/j.ijbiomac.2023.123305. DOI: https://doi.org/10.1016/j.ijbiomac.2023.123305

S. Loganathan and S. Sankaran, "Surface chemical and selective flocculation studies on iron oxide and silica suspensions in the presence of xanthan gum," Minerals Engineering, vol. 160, p. 106668, 2021, doi: https://doi.org/10.1016/j.mineng.2020.106668. DOI: https://doi.org/10.1016/j.mineng.2020.106668

D. Vadibeler, E. Ugwu, N. Martínez-Villegas, and B. Sen Gupta, "Statistical analysis and optimisation of coagulation-flocculation process for recovery of kaolinite and calcium carbonate from suspensions using xanthan gum," Journal of Food Agriculture and Environment, vol. Vol.18 (2):103-109, pp. 103-109, 2020, doi: https://doi.org/10.1234/4.2020.5602.

M. M. Sudirgo, R. A. Surya, H. Kristianto, S. Prasetyo, and A. K. Sugih, "Application of xanthan gum as coagulant-aid for decolorization of synthetic Congo red wastewater," Heliyon, vol. 9, no. 4, p. e15011, 2023, doi: https://doi.org/10.1016/j.heliyon.2023.e15011. DOI: https://doi.org/10.1016/j.heliyon.2023.e15011

M. H. Abu Elella, M. W. Sabaa, E. A. ElHafeez, and R. R. Mohamed, "Crystal violet dye removal using crosslinked grafted xanthan gum," International Journal of Biological Macromolecules, vol. 137, pp. 1086-1101, 2019, doi: https://doi.org/10.1016/j.ijbiomac.2019.06.243. DOI: https://doi.org/10.1016/j.ijbiomac.2019.06.243

A. Kaur and D. Sud, "Thionyl Chloride Facilitated Polymerization of Xanthan Gum Grafted Copolymers for Wastewater Remediation by Exclusion of Synthetic Dyes," Journal of Polymers and the Environment, vol. 30, no. 12, pp. 4978-4998, 2022, doi: https://doi.org/10.1007/s10924-022-02572-5. DOI: https://doi.org/10.1007/s10924-022-02572-5

R. K. Dwari and B. K. Mishra, "Evaluation of flocculation characteristics of kaolinite dispersion system using guar gum: A green flocculant," International Journal of Mining Science and Technology, vol. 29, no. 5, pp. 745-755, 2019, doi: https://doi.org/10.1016/j.ijmst.2019.06.001. DOI: https://doi.org/10.1016/j.ijmst.2019.06.001

S. Singh, J. P. Pandey, and G. Sen, "Microwave assisted synthesis of guar gum based biopolymeric macromolecule optimized as a flocculant for mineral ore processing," International Journal of Biological Macromolecules, vol. 220, pp. 307-315, 2022, doi: https://doi.org/10.1016/j.ijbiomac.2022.08.042. DOI: https://doi.org/10.1016/j.ijbiomac.2022.08.042

D. J. Venegas-García and L. D. Wilson, "Utilization of Bioflocculants from Flaxseed Gum and Fenugreek Gum for the Removal of Arsenicals from Water," Materials, vol. 15, no. 23, doi: https://doi.org/10.3390/ma15238691. DOI: https://doi.org/10.3390/ma15238691

F. A. B. M. Lanan, A. Selvarajoo, V. Sethu, and S. K. Arumugasamy, "Utilisation of natural plant-based fenugreek (Trigonella foenum-graecum) coagulant and okra (Abelmoschus escluentus) flocculant for palm oil mill effluent (POME) treatment," Journal of Environmental Chemical Engineering, vol. 9, no. 1, p. 104667, 2021, doi: https://doi.org/10.1016/j.jece.2020.104667. DOI: https://doi.org/10.1016/j.jece.2020.104667

K. S. Lim, V. Sethu, and A. Selvarajoo, "Natural plant materials as coagulant and flocculants for the treatment of palm oil mill effluent," Materials Today: Proceedings, vol. 48, pp. 871-887, 2022, doi: https://doi.org/10.1016/j.matpr.2021.02.483. DOI: https://doi.org/10.1016/j.matpr.2021.02.483

S. Mishra and K. Kundu, "Synthesis, characterization and applications of polyacrylamide grafted fenugreek gum (FG-g-PAM) as flocculant: Microwave vs thermal synthesis approach," International Journal of Biological Macromolecules, vol. 141, pp. 792-808, 2019, doi: https://doi.org/10.1016/j.ijbiomac.2019.09.033. DOI: https://doi.org/10.1016/j.ijbiomac.2019.09.033

J. Yang, X. Zhang, Q. Lu, L. Wang, X. Hu, and H. Zhang, "Preparation, flocculation and application in sugar refining of eco-friendly dextran-polylysine complex flocculant," Separation and Purification Technology, vol. 306, p. 122673, 2023, doi: https://doi.org/10.1016/j.seppur.2022.122673. DOI: https://doi.org/10.1016/j.seppur.2022.122673

L. Wang, Q.-m. Lu, T. Zeng, J.-w. Yang, X.-q. Hu, and H.-b. Zhang, "Synthesis and characterization of a cationic dextran-based flocculant and its application in bacterial sedimentation," Biochemical Engineering Journal, vol. 185, p. 108535, 2022, doi: https://doi.org/10.1016/j.bej.2022.108535. DOI: https://doi.org/10.1016/j.bej.2022.108535

M. H. Mohamed Noor, N. Ngadi, I. Mohammed Inuwa, L. A. Opotu, and M. G. Mohd Nawawi, "Synthesis and application of polyacrylamide grafted magnetic cellulose flocculant for palm oil wastewater treatment," Journal of Environmental Chemical Engineering, vol. 8, no. 4, p. 104014, 2020, doi: https://doi.org/10.1016/j.jece.2020.104014. DOI: https://doi.org/10.1016/j.jece.2020.104014

G. Guan, T. Gao, X. Wang, and T. Lou, "A cost-effective anionic flocculant prepared by grafting carboxymethyl cellulose and lignosulfonate with acrylamide," Cellulose, vol. 28, no. 17, pp. 11013-11023, 2021, doi: https://doi.org/10.1007/s10570-021-04232-8. DOI: https://doi.org/10.1007/s10570-021-04232-8

X. Feng et al., "Preparation of acrylamide and carboxymethyl cellulose graft copolymers and the effect of molecular weight on the flocculation properties in simulated dyeing wastewater under different pH conditions," International Journal of Biological Macromolecules, vol. 155, pp. 1142-1156, 2020, doi: https://doi.org/10.1016/j.ijbiomac.2019.11.081. DOI: https://doi.org/10.1016/j.ijbiomac.2019.11.081

X. Jiang, C. Lou, F. Hua, H. Deng, and X. Tian, "Cellulose nanocrystals-based flocculants for high-speed and high-efficiency decolorization of colored effluents," Journal of Cleaner Production, vol. 251, p. 119749, 2020, doi: https://doi.org/10.1016/j.jclepro.2019.119749. DOI: https://doi.org/10.1016/j.jclepro.2019.119749

J. Blockx et al., "Cationic Cellulose Nanocrystals for Flocculation of Microalgae: Effect of Degree of Substitution and Crystallinity," ACS Applied Nano Materials, vol. 2, no. 6, pp. 3394-3403, 2019, doi: https://doi.org/10.1021/acsanm.9b00315. DOI: https://doi.org/10.1021/acsanm.9b00315

Z. Wang, W. Huang, G. Yang, Y. Liu, and S. Liu, "Preparation of cellulose-base amphoteric flocculant and its application in the treatment of wastewater," Carbohydrate Polymers, vol. 215, pp. 179-188, 2019, doi: https://doi.org/10.1016/j.carbpol.2019.03.097. DOI: https://doi.org/10.1016/j.carbpol.2019.03.097

D. Morantes, E. Muñoz, D. Kam, and O. Shoseyov, "Highly Charged Cellulose Nanocrystals Applied as A Water Treatment Flocculant," Nanomaterials, vol. 9, no. 2, doi: https://doi.org/10.3390/nano9020272. DOI: https://doi.org/10.3390/nano9020272

X. Xiao, Y. Sun, J. Liu, and H. Zheng, "Flocculation of heavy metal by functionalized starch-based bioflocculants: Characterization and process evaluation," Separation and Purification Technology, vol. 267, p. 118628, 2021, doi: https://doi.org/10.1016/j.seppur.2021.118628. DOI: https://doi.org/10.1016/j.seppur.2021.118628

S. Kang et al., "Starch-derived flocculant with hyperbranched brush architecture for effectively flocculating organic dyes, heavy metals and antibiotics," Journal of the Taiwan Institute of Chemical Engineers, vol. 135, p. 104383, 2022, doi: https://doi.org/10.1016/j.jtice.2022.104383. DOI: https://doi.org/10.1016/j.jtice.2022.104383

S. M. Asharuddin, N. Othman, N. S. M. Zin, H. A. Tajarudin, and M. F. Md Din, "Flocculation and antibacterial performance of dual coagulant system of modified cassava peel starch and alum," Journal of Water Process Engineering, vol. 31, p. 100888, 2019, doi: https://doi.org/10.1016/j.jwpe.2019.100888. DOI: https://doi.org/10.1016/j.jwpe.2019.100888

S. Usefi and M. Asadi-Ghalhari, "Modeling and Optimization of the Coagulation–Flocculation Process in Turbidity Removal from Aqueous Solutions Using Rice Starch," (in en), Pollution, vol. 5, no. 3, pp. 623-636, 2019, doi: https://doi.org/10.22059/poll.2019.271649.552. DOI: https://doi.org/10.1007/s42108-019-00010-2

P. Saranya, S. T. Ramesh, and R. Gandhimathi, "Coagulation performance evaluation of alginate as a natural coagulant for the treatment of turbid water," Water Practice and Technology, vol. 17, no. 1, pp. 395-404, 2021, doi: https://doi.org/10.2166/wpt.2021.123. DOI: https://doi.org/10.2166/wpt.2021.123

Y. H. Yuan, D. M. Jia, and Y. H. Yuan, "Chitosan/Sodium Alginate, a Complex Flocculating Agent for Sewage Water Treatment," Advanced Materials Research, vol. 641-642, pp. 101-104, 2013, doi: 10.4028/www.scientific.net/AMR.641-642.101. DOI: https://doi.org/10.4028/www.scientific.net/AMR.641-642.101

C. Liu et al., "Synthesis, characterization and flocculation performance of a novel sodium alginate-based flocculant," Carbohydrate Polymers, vol. 248, p. 116790, 2020, doi: https://doi.org/10.1016/j.carbpol.2020.116790. DOI: https://doi.org/10.1016/j.carbpol.2020.116790

G. Craciun, E. Manaila, and D. Ighigeanu, "New Type of Sodium Alginate-g-acrylamide Polyelectrolyte Obtained by Electron Beam Irradiation: Characterization and Study of Flocculation Efficacy and Heavy Metal Removal Capacity," Polymers, vol. 11, no. 2, 2019, doi: https://doi.org/10.3390/polym11020234. DOI: https://doi.org/10.3390/polym11020234

Y. Long, X. You, Y. Chen, H. Hong, B.-Q. Liao, and H. Lin, "Filtration behaviors and fouling mechanisms of ultrafiltration process with polyacrylamide flocculation for water treatment," Science of The Total Environment, vol. 703, p. 135540, 2020, doi: https://doi.org/10.1016/j.scitotenv.2019.135540. DOI: https://doi.org/10.1016/j.scitotenv.2019.135540

T. Tripathy, H. Kolya, and S. Jana, "Selective Lead(II) Adsorption and Flocculation Characteristics of the Grafted Sodium Alginate: A Comparative Study," Journal of Polymers and the Environment, vol. 26, no. 3, pp. 926-937, 2018, doi: https://doi.org/10.1007/s10924-017-1004-7. DOI: https://doi.org/10.1007/s10924-017-1004-7

P. D. Choudhary and H. A. Pawar, "Recently Investigated Natural Gums and Mucilages as Pharmaceutical Excipients: An Overview," (in eng), J Pharm (Cairo), vol. 2014, pp. 204849-204849, 2014, doi: https://doi.org/10.1155/2014/204849. DOI: https://doi.org/10.1155/2014/204849

S. Mukherjee, S. Mukhopadhyay, M. Z. B. Zafri, X. Zhan, M. A. Hashim, and B. Sen Gupta, "Application of guar gum for the removal of dissolved lead from wastewater," Industrial Crops and Products, vol. 111, pp. 261-269, 2018/01/01/ 2018, doi: https://doi.org/10.1016/j.indcrop.2017.10.022. DOI: https://doi.org/10.1016/j.indcrop.2017.10.022

A. Nakamura, M. Ozaki, and K. Murakami, "Elucidation of the aggregation mechanism of bentonite with cationic guar gum as flocculant and application to filtration," Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 596, p. 124660, 2020, doi: https://doi.org/10.1016/j.colsurfa.2020.124660. DOI: https://doi.org/10.1016/j.colsurfa.2020.124660

M. V. G. Paixão and R. d. C. Balaban, "Application of guar gum in brine clarification and oily water treatment," International Journal of Biological Macromolecules, vol. 108, pp. 119-126, 2018, doi: https://doi.org/10.1016/j.ijbiomac.2017.11.166. DOI: https://doi.org/10.1016/j.ijbiomac.2017.11.166

R. Srinivasan and A. Mishra, "Okra (Hibiscus esculentus) and fenugreek (Trigonella foenum graceum) mucilage: characterization and application as flocculants for textile effluent treatments," Chinese Journal of Polymer Science, vol. 26, no. 06, pp. 679-687, 2008, doi: https://doi.org/10.1142/S0256767908003424. DOI: https://doi.org/10.1142/S0256767908003424

M. M. J. م. م. حنوص, S. E. S. س. ع. صالح, and K. M. S. ك. م. شبيب, "Coagulation-Flocculation process to treat Pulp and Paper Mill Wastewater by Fenugreek Mucilage Coupled with Alum and Polyaluminum Chloride," Al-Khwarizmi Engineering Journal, vol. 7, pp. 39-47, 2011.

A. Mahto and S. Mishra, "Guar Gum Grafted Itaconic Acid: A Solution for Different Waste Water Treatment," Journal of Polymers and the Environment, vol. 29, no. 11, pp. 3525-3538, 2021, doi: https://doi.org/10.1007/s10924-021-02125-2. DOI: https://doi.org/10.1007/s10924-021-02125-2

G. Nandi, A. Changder, and L. K. Ghosh, "Graft-copolymer of polyacrylamide-tamarind seed gum: Synthesis, characterization and evaluation of flocculating potential in peroral paracetamol suspension," Carbohydrate Polymers, vol. 215, pp. 213-225, 2019, doi: https://doi.org/10.1016/j.carbpol.2019.03.088. DOI: https://doi.org/10.1016/j.carbpol.2019.03.088

H. Mittal, V. Kumar, S. M. Alhassan, and S. S. Ray, "Modification of gum ghatti via grafting with acrylamide and analysis of its flocculation, adsorption, and biodegradation properties," International Journal of Biological Macromolecules, vol. 114, pp. 283-294, 2018, doi: https://doi.org/10.1016/j.ijbiomac.2018.03.131. DOI: https://doi.org/10.1016/j.ijbiomac.2018.03.131

T. Bal et al., "Invitro evaluations of free radical assisted microwave irradiated polyacrylamide grafted cashew gum (CG) biocompatible graft copolymer (CG-g-PAM) as effective polymeric scaffold," Journal of Drug Delivery Science and Technology, vol. 56, p. 101572, 2020, doi: https://doi.org/10.1016/j.jddst.2020.101572. DOI: https://doi.org/10.1016/j.jddst.2020.101572

C. Zhao et al., "Evaluation of a novel dextran-based flocculant on treatment of dye wastewater: Effect of kaolin particles," Science of the Total Environment, pp. 243-254, 2018, doi: https://doi.org/101016/jscitotenv201805286. DOI: https://doi.org/10.1016/j.scitotenv.2018.05.286

R.-h. Li, H.-b. Zhang, X.-q. Hu, W.-w. Gan, and Q.-p. Li, "An efficiently sustainable dextran-based flocculant: Synthesis, characterization and flocculation," Chemosphere, vol. 159, pp. 342-350, 2016, doi: https://doi.org/10.1016/j.chemospherevaluatioe.2016.06.010. DOI: https://doi.org/10.1016/j.chemosphere.2016.06.010

L. Ghimici and M. Nichifor, "Dextran derivatives application as flocculants," Carbohydrate Polymers, vol. 190, pp. 162-174, 2018, doi: https://doi.org/10.1016/j.carbpol.2018.02.075. DOI: https://doi.org/10.1016/j.carbpol.2018.02.075

N. Kutsevol, Y. Kuziv, T. Cabrera, S. M. Husson, T. A. DeVol, and V. Bliznyuk, "Biodegradable star-like polymer flocculants for rapid, efficient purification of water contaminated with industrial radionuclides," Separation and Purification Technology, vol. 273, p. 118630, 2021, doi: https://doi.org/10.1016/j.seppur.2021.118630. DOI: https://doi.org/10.1016/j.seppur.2021.118630

D. Klemm, B. Heublein, H.-P. Fink, and A. Bohn, "Cellulose: Fascinating Biopolymer and Sustainable Raw Material," Angewandte Chemie International Edition, vol. 44, no. 22, pp. 3358-3393, 2005, doi: https://doi.org/10.1002/anie.200460587. DOI: https://doi.org/10.1002/anie.200460587

D. Fauzani, S. Notodarmojo, M. Handajani, Q. Helmy, and T. Kardiansyah, "Cellulose in natural flocculant applications: A review," Journal of Physics: Conference Series, vol. 2047, no. 1, p. 12030, 2021, doi: https://doi.org/10.1088/1742-6596/2047/1/012030. DOI: https://doi.org/10.1088/1742-6596/2047/1/012030

A. Guleria, G. Kumari, and E. C. Lima, "Cellulose-g-poly-(acrylamide-co-acrylic acid) polymeric bioadsorbent for the removal of toxic inorganic pollutants from wastewaters," Carbohydrate Polymers, vol. 228, p. 115396, 2020/01/15/ 2020, doi: https://doi.org/10.1016/j.carbpol.2019.115396. DOI: https://doi.org/10.1016/j.carbpol.2019.115396

M.-L. Song et al., "Multibranch Strategy To Decorate Carboxyl Groups on Cellulose Nanocrystals To Prepare Adsorbent/Flocculants and Pickering Emulsions," ACS Sustainable Chemistry & Engineering, vol. 7, no. 7, pp. 6969-6980, 2019, doi: https://doi.org/10.1021/acssuschemeng.8b06671. DOI: https://doi.org/10.1021/acssuschemeng.8b06671

R. L. Whistler, J. N. BeMiller, and E. F. Paschall, Starch: Chemistry and Technology. Elsevier Science, 2012.

Z. Liu, H. Wei, A. Li, and H. Yang, "Evaluation of structural effects on the flocculation performance of a co-graft starch-based flocculant," Water Research, vol. 118, pp. 160-166, 2017, doi: https://doi.org/10.1016/j.watres.2017.04.032. DOI: https://doi.org/10.1016/j.watres.2017.04.032

K. Wang et al., "Evaluation of renewable pH-responsive starch-based flocculant on treating and recycling of highly saline textile effluents," Environmental Research, vol. 201, p. 111489, 2021, doi: https://doi.org/10.1016/j.envres.2021.111489. DOI: https://doi.org/10.1016/j.envres.2021.111489

P. Maćczak, H. Kaczmarek, and M. Ziegler-Borowska, "Recent Achievements in Polymer Bio-Based Flocculants for Water Treatment," Materials, vol. 13, no. 18, 2020, doi: https://doi.org/10.3390/ma13183951. DOI: https://doi.org/10.3390/ma13183951

L. Ghimici and M. Constantin, "A review of the use of pullulan derivatives in wastewater purification," Reactive and Functional Polymers, vol. 149, p. 104510, 2020, doi: https://doi.org/10.1016/j.reactfunctpolym.2020.104510. DOI: https://doi.org/10.1016/j.reactfunctpolym.2020.104510

K.-Y. Park, D.-Y. Kim, and W.-S. Shin, "Roles of chondroitin sulfate in oil-in-water emulsions formulated using bovine serum albumin," Food Science and Biotechnology, vol. 24, no. 5, pp. 1583-1589, 2015, doi: https://doi.org/10.1007/s10068-015-0204-y. DOI: https://doi.org/10.1007/s10068-015-0204-y

J. Aggarwal, S. Sharma, H. Kamyab, and A. Nadda, "The Realm of Biopolymers and Their Usage: An Overview," pp. 1005-1016, 05/20 2020.

G. Jiao, G. Yu, J. Zhang, and H. S. Ewart, "Chemical structures and bioactivities of sulfated polysaccharides from marine algae," Mar Drugs, vol. 9, no. 2, pp. 196-223, 2011, doi: https://doi.org/10.3390/md9020196. DOI: https://doi.org/10.3390/md9020196

C. Saguez, D. Viterbo, S. Descorps-Declère, B. P. Cormack, B. Dujon, and G.-F. Richard, "Functional variability in adhesion and flocculation of yeast megasatellite genes," Genetics, vol. 221, no. 1, p. iyac042, 2022, doi: https://doi.org/10.1093/genetics/iyac042. DOI: https://doi.org/10.1093/genetics/iyac042

M. Kostag and O. A. El Seoud, "Sustainable biomaterials based on cellulose, chitin and chitosan composites - A review," Carbohydrate Polymer Technologies and Applications, vol. 2, p. 100079, 2021/12/25/ 2021, doi: https://doi.org/10.1016/j.carpta.2021.100079. DOI: https://doi.org/10.1016/j.carpta.2021.100079

PE floc forming mechanisms. A. Particle neutralization methods dependent of   polymer configuration. B. Particle neutralization methods dependent of polymer charge.

Published

2023-05-28

How to Cite

Oropeza-Guzmán, M. T., & Araiza-Verduzco, F. (2023). Evaluación de polisacáridos en floculación mediada por complejo polielectrolítico. Revista De Ciencias Tecnológicas, 6(2), e247. https://doi.org/10.37636/recit.v6n2e247

Most read articles by the same author(s)