Study of photophysical properties of bis-fluorophoreic type sensors and their application in the detection of metal ions

Authors

  • Xiomara Elizabeth Aguilar-Martínez National Technological Institute of Mexico, Technological Institute of Tijuana, Blvd. Alberto Limón Padilla s / n, Mesa de Otay, CP 22500, Tijuana, Baja California, Mexico https://orcid.org/0000-0001-5238-9351
  • Marisela Martínez-Quiroz 319/5000 National Technological Institute of Mexico, Technological Institute of Tijuana, Blvd. Alberto Limón Padilla s / n, Mesa de Otay, CP 22500, Tijuana, Baja California, Mexico CETYS University, Center for Innovation and Design, School of Engineering Av. CETYS University No. 4 Fracc. El Lago, CP 22210, Tijuana, Baja California, Mexico. https://orcid.org/0000-0001-6374-3029
  • Mercedes Teresita Oropeza-Guzmán National Technological Institute of Mexico, Technological Institute of Tijuana, Blvd. Alberto Limón Padilla s / n, Mesa de Otay, CP 22500, Tijuana, Baja California, Mexico https://orcid.org/0000-0001-7399-5529

DOI:

https://doi.org/10.37636/recit.v23124136

Keywords:

Sensor, Fluorophore, Ions, Metals, Water.

Abstract

Industrialized cities like Tijuana dispose of a large amount of water with metallic elements content, as a result of by-products, which represent a health risk. A proposed alternative is the use of chemical sensors based on different mechanisms. The focus of this project is the study of bis-o-aminobenzamide macromolecules, as metal ion selector sensors with application in wastewater treatment. A series of five bis-o-aminobenzamide compounds were studied as chemical sensors capable of selecting and coordinating with metals dissolved in water, in addition to being able to remove these metals in the presence of the natural coagulant Pectin, which was extracted from the penca of the nopal. For this, different concentrations of the five compounds were prepared, the most suitable for the analyzes was selected and it was contacted with solutions of different ions. The compounds and their coordination were evaluated by fluorescence, UV-Visible and Zeta potential spectroscopies. In addition, SEM micrographs were obtained upon removal obtained. The five sensors evaluated have different fluorescence intensities. When in contact with some metal ions, a coordination was formed that reduces the emission of fluorescence. Fluorescent properties in solution were studied by varying the concentration of ligand and the study of its interaction with different metals of environmental interest was carried out. The influence of the nature of the central chain of interconnection on the fluorescent properties of the studied library was determined. These ligands have interesting fluorescent characteristics, which gives them a potential value as sensors for metals, presenting a sensitivity for the Cu +2 ion in all cases.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

References

Programa Mundial de Evaluación de los Recursos Hídricos [WWAP], "El agua en un mundo en constante cambio. El 3er Informe sobre el Desarrollo de los Recursos Hídricos en el Mundo.," p. 16, 2009. http://www.unesco.org/new/es/natural-sciences/environment/water/wwap/display-single-publication/news/water_in_a_changing_world/

Comisión Nacional del Agua (CONAGUA), Manual de agua potable, alcantarillado y saneamiento: Guía para el control de descargas a los sistemas de Alcantarillado urbano o municipal. 2007. https://files.conagua.gob.mx/conagua/mapas/SGAPDS-1-15-Libro31.pdf

J. Garrigos, "El poder del agua morada," Rev. Ing., vol. 28, pp. 141-150, 2011.

R. C. y P. S. de CV, "Plan Integral de Saneamiento y Reúso del Agua en Tijuana y Playas De Rosarito, en el Estado de Baja California," 2017. https://www.cespt.gob.mx/Documentos/Transparencia/Art_81/81_41/41_03_2018_ResumenEstudioSaneamiento.pdf

R. Kumar and R. Singh, Prospect of Graphene for Use as Sensors in Miniaturized and Biomedical Sensing Devices. Elsevier Ltd., 2018. https://doi.org/10.1016/B978-0-12-803581-8.10334-0 DOI: https://doi.org/10.1016/B978-0-12-803581-8.10334-0

C. C. Woodroofe and S. J. Lippard, "A novel two-fluorophore approach to ratiometric sensing of Zn2+," J. Am. Chem. Soc., vol. 125, no. 38, pp. 11458-11459, 2003. https://doi.org/10.1021/ja0364930 DOI: https://doi.org/10.1021/ja0364930

A. C. Somersall and J. E. Guillet, "Photoluminescence of Synthetic Polymers," J. Macromol. Sci. Part C, vol. 13, no. 2, pp. 135-187, 1975. https://doi.org/10.1080/15321797508080008 DOI: https://doi.org/10.1080/15321797508080008

Q. C. Xu, X. H. Zhu, C. Jin, G. W. Xing, and Y. Zhang, "Dual off-on and on-off fluorescent detection of Zn2+/Cd 2+ ions based on carbazolone substituted 2-aminobenzamides," RSC Adv., vol. 4, no. 7, pp. 3591-3596, 2014. https://doi.org/10.1039/C3RA45717F DOI: https://doi.org/10.1039/C3RA45717F

G. Pina-Luis, A. Oehoa-Terán, and I. A. Rivero, "Solid phase synthesis of N-Alkyl-bis-o-aminobenzamides for metal ion sensing based on a fluorescent Dansyl platform," J. Comb. Chem., vol. 11, no. 1, pp. 83-90, 2009. https://doi.org/10.1021/cc8000772 DOI: https://doi.org/10.1021/cc8000772

J. M. Wang, X. Jiang, Y. Zhang, Y. M. Zhu, and J. K. Shen, "Palladium-catalyzed synthesis of 4H-benzo[d][1,3]oxazin-4-ones and N-(2-cyanophenyl)benzamides via tert-butyl isocyanide insertion," Tetrahedron Lett., vol. 56, no. 18, pp. 2349-2354, 2015. https://doi.org/10.1016/j.tetlet.2015.03.121 DOI: https://doi.org/10.1016/j.tetlet.2015.03.121

X. M. Wang et al., "Synthesis and antitumor activities evaluation of m-(4-morpholinoquinazolin-2-yl)benzamides in vitro and in vivo," Eur. J. Med. Chem., vol. 96, pp. 382-395, 2015. https://doi.org/10.1016/j.ejmech.2015.04.037 DOI: https://doi.org/10.1016/j.ejmech.2015.04.037

M. Martinez-quiroz, X. E. Aguilar-martinez, M. T. Oropeza-Guzmán, R. Valdez, and E. A. Lopez-Maldonado, "Evaluation of N -Alkyl-bis- o -aminobenzamide," Molecules, vol. 24, no. 9, p. 1737, 2019. https://doi.org/10.3390/molecules24091737 DOI: https://doi.org/10.3390/molecules24091737

A. Cárdenas, F. M. Goycoolea, and M. Rinaudo, "On the gelling behaviour of 'nopal' (Opuntia ficus indica) low methoxyl pectin," Carbohydr. Polym., vol. 73, no. 2, pp. 212-222, 2008. https://doi.org/10.1016/j.carbpol.2007.11.017 DOI: https://doi.org/10.1016/j.carbpol.2007.11.017

B. Ramachandram, G. Saroja, B. Sankaran, and A. Samanta, "Unusually High Fluorescence Enhancement of Some 1,8-Naphthalimide Derivatives Induced by Transition Metal Salts," J. Phys. Chem. B, vol. 104, no. 49, pp. 11824-11832, 2002. https://doi.org/10.1021/jp000333i

https://doi.org/10.1021/jp000333i DOI: https://doi.org/10.1021/jp000333i

D. Ibarra-Rodríguez, J. Lizardi-Mendoza, E. A. López-Maldonado, and M. T. Oropeza-Guzmán, "Capacity of 'nopal' pectin as a dual coagulant-flocculant agent for heavy metals removal," Chem. Eng. J., vol. 323, pp. 19-28, 2017. https://doi.org/10.1016/j.cej.2017.04.087 DOI: https://doi.org/10.1016/j.cej.2017.04.087

E. A. Chandross and C. J. Dempster, "Intramolecular Excimer Formation and Fluorescence Quenching in Dinaphthylalkanes," J. Am. Chem. Soc., vol. 92, no. 12, pp. 3586-3593, 1970. https://doi.org/10.1021/ja00715a010 DOI: https://doi.org/10.1021/ja00715a010

M. R. Awual and M. M. Hasan, "Colorimetric detection and removal of copper(II) ions from wastewater samples using tailor-made composite adsorbent," Sensors Actuators, B Chem., vol. 206, pp. 692-700, 2015. https://doi.org/10.1016/j.snb.2014.09.086 DOI: https://doi.org/10.1016/j.snb.2014.09.086

Published

2019-09-30

How to Cite

Aguilar-Martínez, X. E., Martínez-Quiroz, M., & Oropeza-Guzmán, M. T. (2019). Study of photophysical properties of bis-fluorophoreic type sensors and their application in the detection of metal ions. REVISTA DE CIENCIAS TECNOLÓGICAS, 2(3), 124–136. https://doi.org/10.37636/recit.v23124136

Issue

Section

Research articles

Categories

Most read articles by the same author(s)