Evaluation of cobalt nanoparticle deposited graphene oxide and carbon nanotube supports as supercapacitor electrodes

Authors

  • David Ricardo Aguilar-Meza National Technological Institute of Mexico, Technological Institute of Tijuana, Postgraduate in Engineering Sciences, Blvd. Industrial S / N. C. P. 22500. Tijuana, Baja California, Mexico. https://orcid.org/0000-0002-7934-0440
  • Moisés Israel Salazar-Gastélum National Technological Institute of Mexico, Technological Institute of Tijuana, Postgraduate in Engineering Sciences, Blvd. Industrial S / N. C. P. 22500. Tijuana, Baja California, Mexico.
  • Sergio Pérez-Sicairos National Technological Institute of Mexico, Technological Institute of Tijuana, Postgraduate in Engineering Sciences, Blvd. Industrial S / N. C. P. 22500. Tijuana, Baja California, Mexico. National Technological Institute of Mexico, Technological Institute of Tijuana, Center for Graduates and Research in Chemistry, Blvd. Industrial S / N. C. P. 22500. Tijuana, Baja California, Mexico. https://orcid.org/0000-0002-1244-3015
  • Rosa María Félix-Navarro National Technological Institute of Mexico, Technological Institute of Tijuana, Center for Graduates and Research in Chemistry, Blvd. Industrial S / N. C. P. 22500. Tijuana, Baja California, Mexico. https://orcid.org/0000-0002-0303-0614
  • Yadira Gochi-Ponce National Technological Institute of Mexico, Technological Institute of Tijuana, Postgraduate in Engineering Sciences, Blvd. Industrial S / N. C. P. 22500. Tijuana, Baja California, Mexico. National Technological Institute of Mexico, Technological Institute of Tijuana, Center for Graduates and Research in Chemistry, Blvd. Industrial S / N. C. P. 22500. Tijuana, Baja California, Mexico. https://orcid.org/0000-0002-1590-2432

DOI:

https://doi.org/10.37636/recit.v214044

Keywords:

Supercapacitor, Graphene Oxide, Carbon Nanotubes, Cobalt Nanoparticles.

Abstract

Cobalt nanoparticles were deposited on multi-wall carbon nanotubes (CNT) and graphene oxide (GO) carbon supports and evaluated as a potential supercapacitor electrodes. The structure and morphology of the cobalt nanoparticles deposited on carbon supports were studied using XRD, TGA, and Raman spectroscopy. Cyclic voltammetry was used to measure the electrical charge of the electrode based on the materials and their specific capacitance (Csp) were calculated. GO based electrode showed a higher Csp than CNT electrode which is attributed to a larger surface area of the GO carbon support. Interestingly, the deposition of Co nanoparticles promoted an enhanced Csp in the both GO and multi-wall CNT supports.

Downloads

Download data is not yet available.

References

M. Vangari, T. Pryor, and L. Jiang, "Supercapacitors: Review of materials and fabrication methods," J. Energy Eng., vol. 139, no. 2, pp. 72-79, 2013. https://doi.org/10.1061/(ASCE)EY.1943-7897.0000102 DOI: https://doi.org/10.1061/(ASCE)EY.1943-7897.0000102

C. Zhao and W. Zheng, "A Review for Aqueous Electrochemical Supercapacitors," Front. Energy Res., vol. 3, no. May, pp. 1-11, 2015. https://doi.org/10.3389/fenrg.2015.00023 DOI: https://doi.org/10.3389/fenrg.2015.00023

Z. Fan, J. Chen, K. Cui, F. Sun, Y. Xu, and Y. Kuang, "Preparation and capacitive properties of cobalt-nickel oxides/carbon nanotube composites," Electrochim. Acta, vol. 52, no. 9, pp. 2959-2965, 2007. https://doi.org/10.1016/j.electacta.2006.09.029 DOI: https://doi.org/10.1016/j.electacta.2006.09.029

W. Chen, L. Yan, and P. R. Bangal, "Preparation of graphene by the rapid and mild thermal reduction of graphene oxide induced by microwaves," Carbon N. Y., vol. 48, no. 4, pp. 1146- 1152, 2010. https://doi.org/10.1016/j.carbon.2009.11.037 DOI: https://doi.org/10.1016/j.carbon.2009.11.037

A. Aguilar-Elguézabal, W. Antúnez, G. Alonso, F. P. Delgado, F. Espinosa, and M. Miki- Yoshida, "Study of carbon nanotubes synthesis by spray pyrolysis and model of growth," Diam. Relat. Mater., vol. 15, no. 9, pp. 1329-1335, 2006. https://doi.org/10.1016/j.diamond.2005.10.011 DOI: https://doi.org/10.1016/j.diamond.2005.10.011

M. Beltrán Gastélum, "Síntesis y caracterización de electrocatalizadores nanoestructurados y su aplicación en celdas de combustible a escala prototipo," Instituto Tecnológico de Tijuana, 2016.

S. Perumbilavil, P. Sankar, T. Priya Rose, and R. Philip, "White light Z-scan measurements of ultrafast optical nonlinearity in reduced graphene oxide nanosheets in the 400-700 nm region," Appl. Phys. Lett., vol. 107, no. 5, pp. 10-15, 2015. https://doi.org/10.1063/1.4928124 DOI: https://doi.org/10.1063/1.4928124

M. A. Atieh, O. Y. Bakather, B. Al- Tawbini, A. A. Bukhari, F. A. Abuilaiwi, and M. B. Fettouhi, "Characterization of carbon nanotubes by Raman spectroscopy," Bioinorg. Chem. Appl., vol. 2010, no. 2, pp. 1-9, 2010. https://doi.org/10.1155/2010/603978 DOI: https://doi.org/10.1155/2010/603978

T. A. Saleh, The Role of Carbon Nanotubes in Enhancement of Photocatalysis, in Syntheses and Applications of Carbon Nanotubes and Their Composites, S. Suzuki, Ed. Rijeka: InTech, 2013. https://doi.org/10.5772/51050 DOI: https://doi.org/10.5772/51050

V. V. Brus, A. K. K. Kyaw, P. D. Maryanchuk, and J. Zhang, "Quantifying interface states and bulk defects in high-efficiency solution- processed small-molecule solar cells by impedance and capacitance characteristics," Prog. Photovoltaics Res. Appl., vol. 23, no. 11, pp. 1526- 1535, Nov. 2015. https://doi.org/10.1002/pip.2586 DOI: https://doi.org/10.1002/pip.2586

XRD Patterns of CNT, Co/CNT, GOx, and Co/GOx.

Published

2019-02-15

How to Cite

Aguilar-Meza, D. R., Salazar-Gastélum, M. I., Pérez-Sicairos, S., Félix-Navarro, R. M., & Gochi-Ponce, Y. (2019). Evaluation of cobalt nanoparticle deposited graphene oxide and carbon nanotube supports as supercapacitor electrodes. Revista De Ciencias Tecnológicas, 2(1), 40–44. https://doi.org/10.37636/recit.v214044

Issue

Section

Research articles

Categories

Most read articles by the same author(s)